On-Demand Deposition of Diamond-Like-Carbon for Enhanced Friction Reduction

NU 2014-096

 

Primary Investigator

Q. Jane Wang

 

Short Description

A lubrication technology that applies or replenishes a protective layer of carbon on metal parts within engines and drivetrains without requiring disassembly of the machinery.

 

Abstract

Northwestern researchers have developed a novel approach for in-situ and on-demand deposition of lubricious diamond-like-carbon (DLC) onto metal surfaces.  This approach is based on the thermal decomposition of alcohols or carboxylic acids with strained hydrocarbon rings activated by frictional heating.  Control of the threshold decomposition temperature can be tuned by adding spacer groups between the surface-active site and meta-stable hydrocarbon rings of the precursor.  These oil additives provide a unique solution to boundary lubrication by providing DLC coatings to surfaces without the need to disassemble the engine or machine.  Initial ball-on-disk (52100 bearing steel) tribometer data show average friction reduction of 5% with a significant reduction in friction spikes due to asperity contact (see figure below).  Minimizing asperity contact has also shown to decrease wear coefficient of stainless steel by an order of magnitude.  After the initial introduction and thermolysis of the DLC precursor, friction and wear reduction are maintained after multiple rounds of lubricant replacement with no additional additive needed.

 

Stage of Development

Proof of concept experiments have been completed.  Technology is ready for industry-specific testing.

 

Applications

  • Friction and wear reduction at lubricated interfaces
    • Automobile engines
    • Industrial manufacturing
    • Spray lubricants
    • Chain or gear-drive lubricants
    • Turbine lubrication
    • Sealed bearing lubrication

 

Advantages

  • No need for engine or machinery disassembly
  • On-demand lubrication & deposition during operation, so no down-time is required
  • Ability to repair micro-imperfections in coatings or replenish old DLC coatings
  • Compatible properties that do not ruin catalytic converters in automotive applications
  • Long-lasting DLC localization at metal surface without agglomeration in the lubricant

 

IP Status

US and International patents have been filed for composition of matter and methods of use.  PCT/US2015/056965

 

Patent Information: